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Journal of Physical Studies 4(3), 355–365 (2000)
DOI: https://doi.org/10.30970/jps.04.355 THE DISTRIBUTION FUNCTION AND STABILITY CONDITIONS OF POLYMER COMPLEXES OF URANILE WITH DOUBLE BRIDGES OF HYDROGEN BONDSI. V. Stasyuk, Т. V. Golubets'
Institute for Condensed Matter Physics of National Academy of Sciences
of Ukraine, |
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The simple quantum-statistical model for the description of uranile UO$_2^{2+}$ polymerization in water solution with the participation of hydrogen bonds is proposed. The distribution functions of UO$_2${[(OH)$_2$UO$_2$]}$_n^{2+}$ hydroxo-complexes for the length are constructed at the various values of $pH$ level acidity or alkalinity solution with consideration of statistical distribution of protons at the ends of complex and configurational character of interaction between ionic groups in the polymer chain. In terms of the ideal solution approach the general stability conditions of polymer chain formation of various length are determined.
PACS number(s): 82.30.Nr, 36.20.-r, 82.35.+t