DOI: https://doi.org/10.30970/jps.01.418
ORIENTATIONAL-TUNNELING MODEL OF ONE–DIMENSIONAL MOLECULAR SYSTEMS WITH HYDROGEN BONDS
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Journal of Physical Studies 1(3), 418–430 (1997)
DOI: https://doi.org/10.30970/jps.01.418 ORIENTATIONAL-TUNNELING MODEL OF ONE–DIMENSIONAL MOLECULAR SYSTEMS WITH HYDROGEN BONDS |
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I. V. Stasyuk, O. L. Ivankiv, N. I. Pavlenko
Institute for Condensed Matter Physics of the National Academy
of Sciences of Ukraine,
1 Svientsitskii Str., UA-290011 Lviv, Ukraine
The orientational-tunneling model of linear hydrogen-bonded systems with strong short-range proton correlations is developed in the context of problems of proton dynamics and proton transfer. The proton translational motion on a single bond and the Bjerrum orientational jumps are taken into account. The influence of reorientational motion as well as external electric field on energy spectrum and thermodynamical functions of finite linear H-bonded complexes is investigated. Within the framework of the model proposed the systems with $L$- and $D$-proton defects are described.